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Olefination of Furans and Unactivated Alkenes

Olefination of Furans and Unactivated Alkenes Branched vinylfurans formed in high yields and with high selectivities by oxidative olefination of furans with unactivated alkenes Read more...

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Novel Nickel-Based Catalyst Efficiently Splits Water

Originally posted on Green Chemistry International: Researcher discovers inexpensive catalyst to produce oxygen and hydrogen gas. (Credit: Kathy F. Atkinson / University of Delaware) The University of...

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Chitosan: an efficient recyclable catalyst for transamidation of carboxamides...

  Chitosan: an efficient recyclable catalyst for transamidation of carboxamides with amines under neat conditions...

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Seeds Sprout Select Nanotubes Nanotechnology: Chemists create just one type...

A polycyclic aromatic hydrocarbon seed folds up into a cap when heated on a platinum surface. This cap dictates the chirality of the nanotube, approximately 2 nm in diameter, that grows from it....

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Regioselective acetylation of carbohydrates and diols catalyzed by...

Regioselective acetylation of carbohydrates and diols catalyzed by tetramethyl-ammonium hydroxide in water Green Chem., 2014, Advance Article DOI: 10.1039/C4GC00770K, Communication Yuchao Lu,a   Peng...

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Directing Venom To Fight Cancer ACS Meeting News: Encapsulated venom peptide...

  Scorpion toxins may one day be useful as anticancer drugs. Credit: Courtesy of Dipanjan Pan Venom from scorpions or honeybees sounds like it wouldn’t do a person much good. But by directing a...

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Delta12-prostaglandin J3 synthesis

Originally posted on Naturalproductman's Blog: Nicolaou and co-workers have reported in ACIE on the synthesis of delta12-prostaglandin J3. ACIE paper View original

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Green Lab Notebook app now available on iTunes

Originally posted on Cheminformatics 2.0: After somewhat more delay than I would have liked, the Green Lab Notebook (GLN) app is now live and available on the iTunes AppStore. The feature set that...

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CO2 as a protecting group?

Originally posted on Naturalproductman's Blog: Arjan Kleij and co-workers from ICIQ in Spain have reported in ACIE on the use of carbon dioxide as a protecting group for cis-diols arising from...

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ENDO EXO STORY…….cis-norborene-5,6-endo-dicarboxylic anhydride

ENDO EXO STORY…….cis-norborene-5,6-endo-dicarboxylic anhydride   You will react cyclopentadiene with maleic anhydride to form the Diels-Alder product below. This Diels-Alder reaction produces almost...

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Cocrystals of telmisartan: characterization, structure elucidation, in vivo...

Originally posted on New Drug Approvals: Cocrystals of telmisartan: characterization, structure elucidation, in vivo and toxicity studies   CrystEngComm, 2014, 16,8375-8389DOI: 10.1039/C4CE00797B,...

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Structural characterization of form I of anhydrous rifampicin

Originally posted on New Drug Approvals: Structural characterization of form I of anhydrous rifampicin   CrystEngComm, 2014, 16,8555-8562DOI: 10.1039/C4CE01157K, Paper Amanda Laura Ibiapino, Rafael...

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New cocrystals of ezetimibe with L-proline and imidazole

Originally posted on New Drug Approvals: New cocrystals of ezetimibe with L-proline and imidazole   CrystEngComm, 2014, Advance ArticleDOI: 10.1039/C4CE01127A, Paper Manishkumar R. Shimpi, Scott L....

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Synthesis of gamma-decalactone from 1-octene and iodoacetic acid ethyl ester

Synthesis of gamma-decalactone from 1-octene and iodoacetic acid ethyl ester   + Cu   +     Synthesis of gamma-decalactone from 1-octene and iodoacetic acid ethyl ester (batch scale 10 mmol)...

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Scandium-catalyzed hydroarylation

Originally posted on Naturalproductman's Blog: Zhaomin Hou and co-workers from RIKEN have reported in JACS on an enantioselective hydroarylation using a scandium complex.JACS paper View original

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Palladium catalyzed decarboxylative cycloaddition

Originally posted on Naturalproductman's Blog: Yong Jian Zhang and co-workers at Shanghai Jiao Tong University have reported in ACIE on a palladium catalyzed decarboxylative cycloaddition. ACIE paper...

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What’s with aminoquinoline directing groups all of a sudden?

Originally posted on Colorblind Chemistry: Seriously, did someone start giving 8-aminoquinoline away for free?   I started noticing a particular trend in the ASAPs of some of the organic journals I...

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From Termite Fumigant to Molecular Coupling………. Sulfur fluoride exchange – a...

  From Termite Fumigant to Molecular Coupling Sulfur fluoride exchange – a powerful new reaction for click chemistry Sulfur Fluoride Exchange – a Powerful New Reaction A team led by Sharpless at The...

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Synthesis of 2-dimethylaminomethyl-cyclohexanone hydrochloride

Synthesis of 2-dimethylaminomethyl-cyclohexanone hydrochloride http://orgspectroscopyint.blogspot.in/2014/09/synthesis-of-2-dimethylaminomethyl.html++ EtOH, HCl   Synthesis of...

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Asymmetric metathesis

Originally posted on Naturalproductman's Blog: Grubbs and colleagues have reported in JACS on their studies with asymmetric ring closing metathesis. JACS paper View original

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